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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. <t>White</t> <t>light</t> is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.
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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. <t>White</t> <t>light</t> is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.
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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. <t>White</t> <t>light</t> is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.
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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. <t>White</t> <t>light</t> is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.
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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. <t>White</t> <t>light</t> is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.
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Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. White light is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.

Journal: Energy & Environmental Science

Article Title: Reconstructing the electrochemistry of lithium-ion batteries through operando diffuse reflectance spectroscopy

doi: 10.1039/d6ee00376a

Figure Lengend Snippet: Setup for the operando monitoring of the reflectance of battery electrodes. (a) When light is incident on a surface two types of reflection are usually obtained: specular – where the angle of incidence is equal to the angle of reflectance ( e.g. , a polished surface such as a glass window), and diffuse – where incident light is scattered in different directions ( e.g. , a rough surface such as a battery electrode). The light reflected by a battery electrode also changes as a function of SoC. (b) In this study, a windowed coin cell is mounted on an integrating sphere. White light is incident on the coin cell. Specular reflection (from the glass window) is eliminated through a gloss trap while scattered diffuse light (from the electrode) undergoes Lambertian reflection in the sphere until it enters the optical fibre leading to the spectrometer. (c) The reflectance spectrum of LMO vs. Li at different SoCs, with reference to the spectrum at 0% SoC. The reflectance troughs (or absorption peaks) seen at 560 nm and 725 nm for LMO have been previously reported as corresponding to electronic transition between Mn 3d states. (d) Comparing the cost and footprint of DRS with other major operando techniques such as NMR, XRD, and optical microscopy. The lower cost and footprint of DRS could enable parallel screening of several cells under (temperature) controlled conditions, as shown in the left sketch.

Article Snippet: Confocal images were obtained through a commercial, white-light microscope (Lasertec Co. ECCS B-320).

Techniques: Operando Spectroscopy, Battery, Microscopy